Affordable Access

Publisher Website

Tetra­carbonyl­bis(η5-cyclo­penta­dienyl)bis[(dec-9-en-1-yl)diphenyl­phosphine]dimolybdenum(0)(Mo—Mo) tetra­hydro­furan disolvate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
12
Identifiers
DOI: 10.1107/s1600536809046327
Keywords
  • Metal-Organic Papers

Abstract

The asymmetric unit of the title compound, [Mo2(η5-C5H5)2(C22H29P)2(CO)4]·2C4H8O, contains two half-mol­ecules of the organometallic species and two solvent mol­ecules. Both organometallic mol­ecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo—Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by an η5-cyclo­pentdienyl ligand, two carbonyl ligands, and a (dec-9-en-1-yl)diphenyl­phosphine ligand.

There are no comments yet on this publication. Be the first to share your thoughts.