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Thermodynamics of cycloalkane-1,1-dicarboxylic acids in aqueous solution

Authors
Journal
Thermochimica Acta
0040-6031
Publisher
Elsevier
Publication Date
Volume
12
Issue
1
Identifiers
DOI: 10.1016/0040-6031(75)85003-9
Disciplines
  • Physics

Abstract

Abstract The proton ionization in (Na, H)ClO 4 0.1 M aqueous solution of cycloalkane- 1,1-dicarboxylic acids at 25°C was studied by means of potentiometric and calorimetric measurements. The thermodynamic functions p K, Δ G, Δ H and Δ S were obtained. The Δ S values were discussed in terms of solute-solvent interaction changes related to the conformational features of the acids.

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