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Formation of NH(c1Π), NH(A3Π) and NCO(A2Σ) in the VUV photolysis of HNCO

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
166
Identifiers
DOI: 10.1016/0009-2614(90)87136-f
Disciplines
  • Physics

Abstract

Abstract Photodissociative excitation processes of gaseous HNCO are studied in the wavelength region 107–180 nm using synchrotron radiation as a light source. Fluorescence excitation spectra of the photofragments, NH(c 1Π, A 3Π) and NCO(A 2Σ), are measured under near collision-free conditions. The quantum yields for formation of these excited radicals are also determined.

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