Affordable Access

Publisher Website

Bis(2,2′-bipyridyl-κ2 N,N′)(sulfato-κ2 O,O′)zinc(II) ethane-1,2-diol solvate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
66
Issue
2
Identifiers
DOI: 10.1107/s1600536809055433
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

The title compound, [Zn(SO4)(C10H8N2)2]·C2H6O2, is a six-coordinate zinc(II) complex with a distorted octa­hedral coordination geometry. The ZnII atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO4(C10H8N2)2] and C2H6O2 units are connected by inter­molecular O—H⋯O hydrogen bonding, which leads to additional stabilization of the structure.

There are no comments yet on this publication. Be the first to share your thoughts.

Statistics

Seen <100 times
0 Comments

More articles like this

Bis(2,2'-bipyridyl-κN,N')(sulfato-κO,O')zinc(II) e...

on Acta Crystallographica Section... 2010

Bis(2,2′-bipyridyl-κ2 N,N′)(sulfato-κ2 O,O′)cobalt...

on Acta Crystallographica Section... Aug 12, 2010

Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)n...

on Acta Crystallographica Section... Jan 08, 2009

Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)z...

on Acta Crystallographica Section... Jan 05, 2010
More articles like this..