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Transition metal complexes in organic synthesis, part 32. Fluxionality of (η4-1-aza-1,3-butadiene)tricarbonyliron complexes

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
37
Issue
36
Identifiers
DOI: 10.1016/0040-4039(96)01446-3

Abstract

Abstract The fluxionality of tricarbonyliron transfer reagents was investigated and the free enthalpy of activation for the rotation of the tricarbonyliron fragment of ( η 4-1- p-anisyl-4-phenyl-1-aza-1,3-butadiene)tricarbonyliron 4b was determined to 13.8 ± 0.5 kcal/mol.

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