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5-formyl-δ—valerolactone : A useful synthon for the chiral synthesis of thevespa orientalispheromone and the mosquito oviposition attractant pheromone

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
35
Issue
45
Identifiers
DOI: 10.1016/s0040-4039(00)74412-1

Abstract

Abstract A synthetic scheme starting from the reaction between the lithiated N-allyl-N-methyl-(bisdimethylamino)phosphoramide anion and the triflate derivative of ( R)-(-)- or ( S)-(+)-2,3- O-isopropylideneglycerol is described to prepare the key chiral synthon ( R)-5- or ( S)-5-formyl-δ-valerolactone that leads to the title compounds.

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