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Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-κN,O}cobalt(II).

Authors
  • Jiang, Wei
  • Mo, Gui-Di
  • Jin, Lie
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
Publisher
International Union of Crystallography
Publication Date
Jan 01, 2008
Volume
64
Issue
Pt 11
Identifiers
DOI: 10.1107/S1600536808032303
PMID: 21580845
Source
Medline
License
Unknown

Abstract

In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolate ligands, displaying a distorted tetra-hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol-ecular symmetry of the complex is C(2). The two phenolate rings are perpendicular [89.8 (3)°].

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