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Bis[μ-1,1'-(ferrocene-1,1'-di-yl)bis(butane-1,3-dionato)]di-μ-methanol-diiron(II).

Authors
Type
Published Article
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
Pt 6
Identifiers
DOI: 10.1107/S1600536809016353
PMID: 21582994
Source
Medline

Abstract

The asymmetric unit of the title compound, [Fe(4)(C(9)H(8)O(2))(4)(CH(3)OH)(2)], contains one half-mol-ecule located on a twofold rotational axis. In the mol-ecule, the two Fe(II) ions bridged by two coordinating methanol mol-ecules are separated by 3.1286 (7) Å. Two crystallographically independent methanol mol-ecules are situated on a twofold rotational axis; all attached H atoms are rotationally disordered between two equal orientations.

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