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Synthesis of vinyl ethers by homologation of aldehydes via radical reductive elimination

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
25
Issue
52
Identifiers
DOI: 10.1016/s0040-4039(01)81742-1

Abstract

Abstract Methoxyphenylthiomethyllithium 1 reacts with aldehydes to give adducts which are then transformed into xanthates. These compounds, by reaction with tri-n-butylstannane, afford vinyl ethers in good yields.

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