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Rotationally resolved spectroscopy of deuterated fluorene and the fluorene—argon van der Waals complex

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
147
Issue
1
Identifiers
DOI: 10.1016/0009-2614(88)80214-8

Abstract

Abstract With a single frequency tunable UV source in combination with a collimated molecular beam, rovibronic fluorescence spectra were obtained for fully deuterated fluorene and its van der Waals complex with argon. The O 0 0 vibronic band in both molecules was assigned and molecular constants derived. The argon atom in the complex lies above the middle ring of the fluorene molecule. It is shown that substantial zero-point motions are present in the complex, hindering a precise determination of the effective structure.

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