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Transition metal–saccharide chemistry: synthesis, characterization and solution stability studies ofcis-dioxomolybdenum saccharide complexes

Authors
Journal
Carbohydrate Research
0008-6215
Publisher
Elsevier
Publication Date
Volume
311
Issue
3
Identifiers
DOI: 10.1016/s0008-6215(98)00186-4
Keywords
  • Transition Metal–Saccharide Chemistry
  • Cis-Dioxomolybdenum Saccharides
  • Solution Stability
  • Dimeric Structure
  • Bridging Saccharide Units

Abstract

Abstract Six cis-dioxomolybdenum(VI) complexes of simple monosaccharides ( d-glucose, d-fructose, d-galactose, d-mannose, d-ribose and d-xylose) have been synthesized and characterized by a variety of analytical and spectral methods. Both the solution and solid-state studies have supported the presence of dimeric structures, formed through the cis-MoO 2 moieties and the bridging saccharide units. Solution stability of these complexes as a function of time has also been addressed.

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