Affordable Access

Publisher Website

Effect of preoxidation and sintering on properties of ilmenite concentrates

Authors
Journal
International Journal of Mineral Processing
0301-7516
Publisher
Elsevier
Publication Date
Volume
64
Issue
4
Identifiers
DOI: 10.1016/s0301-7516(01)00055-2
Keywords
  • Ilmenite
  • Preoxidation
  • Sintering

Abstract

Abstract The paper examines the effects of preoxidation and sintering on the phase composition, specific surface area, morphology and reducibility of ilmenite concentrates. Samples were preoxidised in air or sintered in argon by temperature-programmed heating to temperatures of 600–1400°C at a ramping rate of 300°C/h. In the concentrates preoxidised at temperatures up to 800°C, ilmenite formed an intermediate product, Fe 2O 3·2TiO 2, which decomposed into Fe 2O 3 and TiO 2. At temperatures above 800°C, pseudorutile was transformed into ferric pseudobrookite and rutile. Haematite recombined with rutile to form pseudobrookite at temperatures above 1000°C. When samples were heated in an argon atmosphere, ferric–ferrous pseudobrookite solid solution was formed from ilmenite and pseudorutile. Preoxidation and sintering at temperatures above 600°C caused a sharp decrease in the specific surface area of samples. The specific surface area decreased by more than 97% when samples were heated to 1200°C. Preoxidation enhanced while sintering retarded the reduction of iron oxides in ilmenite concentrates by methane–hydrogen gas mixtures in the temperature range of 550–800°C. Both preoxidation and sintering increased the temperature required to reduce titanium oxides. At high temperatures, such as 1200°C, the effects of preoxidation and sintering on isothermal reduction of ilmenites were negligible.

There are no comments yet on this publication. Be the first to share your thoughts.