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catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ2 S,S′)nickel(II)]-μ-bis­(4-pyridylmethyl­ene)diazane-κ2 N:N′]

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
11
Identifiers
DOI: 10.1107/s1600536809043505
Keywords
  • Metal-Organic Papers

Abstract

The Ni atom in the title linear supra­molecular polymer, [Ni(C6H14O2PS2)2(C12H10N4)]n, exists within a trans-N2S4 octa­hedral donor set defined by two symmetrically coordinating dithio­phosphate ligands and pyridine N atoms derived from two bridging bis­(4-pyridylmethyl­ene)diazane ligands. The Ni atom lies on a centre of inversion and the bis­(4-pyridylmethyl­ene)diazane ligand is also disposed about a centre of inversion. The chains are arranged into layers sustained by C—H⋯S contacts and inter­digitate with neighbouring layers, forming the crystal structure.

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