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Spin trapping reactions with nitric oxides II. Acylalkyl nitroxides

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
27
Issue
32
Identifiers
DOI: 10.1016/s0040-4039(00)83874-5

Abstract

Abstract Radical trapping by nitric oxide in the presence of oxygen has been studied by ESR spectroscopy. The oxygen was found to react much faster with alkyl radicals than nitric oxide, it suppresses formation of dialkyl nitroxides and initiates creation of acyl nitroxides through reactions between peroxy radicals and nitric oxide.

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