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Phenomenological analysis of phase transitions in epitaxial perovskite ferroelectric thin films

Authors
Journal
Physica B Condensed Matter
0921-4526
Publisher
Elsevier
Publication Date
Volume
405
Issue
7
Identifiers
DOI: 10.1016/j.physb.2010.01.070
Keywords
  • Ferroelectrics
  • Thin Films
  • Phase Transition
  • Epitaxial Strain
  • Phenomenology
Disciplines
  • Philosophy
  • Physics

Abstract

Abstract A phenomenological Landau–Ginzburg–Devonshire theory is employed to investigate the effect of biaxial misfit strains and in-plane shear strain on thermodynamic equilibrium states and dielectric properties of single domain KNbO 3, BaTiO 3, and PbTiO 3 thin films. For KNbO 3 thin films grown on cubic substrates, the constructed isotropic misfit strain–temperature phase diagram is in qualitative agreement with the result from first-principle calculations. For BaTiO 3 and PbTiO 3, misfit strain–temperature phase diagrams at constant in-plane shear strains are constructed. In-plane shear strain is shown to restrain formation of a phase (polarization along [1 0 0]). The anisotropic misfit strain–temperature and misfit strain–misfit strain phase diagrams are also developed for KNbO 3 thin films grown on orthorhombic substrates. The anisotropic biaxial misfit strains lead to appearance of orthorhombic phases (a 1, a 2) and monoclinic phases (a 1c, a 2c).

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