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Chiral propionate enolate equivalents for the stereoselective synthesis ofthreo- orerytho-α,-methyl-β-hydroxy acids

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
26
Issue
17
Identifiers
DOI: 10.1016/s0040-4039(00)94797-x

Abstract

Abstract The aluminium and copper enolates derived from (η 5-C 5H 5)Fe(CO)(PPh 3)COCH 2CH 3 are chiral propionate enolate equivalents which on reaction with aldehydes (RCHO, RMe.Et, iPr, tBu) provide stereoselective syntheses of threo- and erytho-α-methyl-β-hydroxy acids respectively.

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