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Entropy production in electrochemical systems of non-uniform pressure

Authors
Journal
Electrochimica Acta
0013-4686
Publisher
Elsevier
Publication Date
Volume
32
Issue
11
Identifiers
DOI: 10.1016/0013-4686(87)90020-x
Disciplines
  • Chemistry

Abstract

Abstract It is shown how the expression for the entropy production in an electrochemical system has to be generalized so to include the case of non-uniform pressure. Then the statement about the equalization of pressures follows from the non-negative character of the entropy production, just as do the other statements about irreversible processes inside the system.

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