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New synthesis of the cyclic tetrapeptide tentoxin employing an azlactone as key intermediate

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
36
Issue
25
Identifiers
DOI: 10.1016/0040-4039(95)00762-2

Abstract

Abstract An improved preparation of the cyclic tetrapeptide Tentoxin is reported employing an azlactone as key intermediate. This new synthetic route offers the advantage over existing methodologies that the dehydro amino acid would easily be varied, thus allowing the simple preparation of analogues.

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