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Chemical modification of poly(ethylene imine) for polymeric electrolyte

Authors
Journal
Solid State Ionics
0167-2738
Publisher
Elsevier
Publication Date
Identifiers
DOI: 10.1016/0167-2738(86)90134-7
Disciplines
  • Chemistry

Abstract

Abstract Linear PEI has been chemically modified in an attempt to prevent formation of a crystalline complex without altering its ability to dissolve salts and conduct ions. Three main systems were investigated: (a) poly(N-acetylethylene imine), (b) partially quaternized PEI with ethyl or butyl groups, and (c) PEI cross-linked with diepoxyoctane. Dissolution of salt was followed by x-ray diffraction on the mixtures and changes in T g as determined by DSC. In all cases, the crystallinity was destroyed but conductivity of salt-containing polymer was not improved. However, lightly cross-linked PEI exhibits much improved mechanical properties and the incorporation of .05 mole NaI/mole of monomer yields a conductivity of 5×10 −5 S/ cm at 100 °C.

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