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Reactivity of vanadium(V) polymeric and monomeric forms in complex formation withp-phenetidine

Authors
Journal
Inorganica Chimica Acta
0020-1693
Publisher
Elsevier
Publication Date
Volume
5
Identifiers
DOI: 10.1016/s0020-1693(00)95885-7

Abstract

Abstract The formation of charge-transfer complex (CTC) between p-phenetidine and vanadium(V) species existing in acid medium at low vanadium(V) concentrations was studied. It was found that while the CTC formation rate is very low VO 2 +, it is maximal when decavanadate species are used. The results were interpreted on the ground of the electrostatic interaction between the reagents. The rate of depolymerisation of decavanadate species to VO 2 + and H 2VO 4 − was also studied and the rate constants of these processes estimated.

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