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Calculation of the relative stability and strengths of particular bonds in polyphenylene sulphides

Authors
Journal
Polymer Science U S S R
0032-3950
Publisher
Elsevier
Publication Date
Volume
30
Issue
1
Identifiers
DOI: 10.1016/0032-3950(88)90257-2

Abstract

Abstract The energies of atomization, formation and strength of particular bonds of 22 polymer structures based on polyphenylene sulphides and polyphenylenes are calculated within the framework of an interacting bond model. The effect of isomerism and substituents on the bond strength along the polymer backbone is discussed. The polydibenzothiophene and polythianthrene structures are the most stable forms of polyphenylene sulphides. On substitution of hydrogen atoms in polyphenylene sulphides by phenyl groups the strength of the CS bond along the main polymer backbone is changed.

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