Affordable Access

Publisher Website

Complexes of cobalt(II), nickel(II), copper(II), and zinc(II) with the tripod-like ligands tris (2-methylthioethyl)amine

Authors
Journal
Inorganica Chimica Acta
0020-1693
Publisher
Elsevier
Publication Date
Volume
2
Identifiers
DOI: 10.1016/s0020-1693(00)87057-7

Abstract

Abstract The preparation and properties of nine complexes formed by the quadridentate ligand tris(2-methylthioethyl)amine, TSN, and the halides or thiocyanate of cobalt(II), nickel(II), copper(II), and zinc(II) have been studied. The cobalt complexes are formulated as [CoX(TSN)] 2[CoX 4] thus containing both high-spin five-coordinated cobalt and tetrahedral cobalt. The compounds NiX 2(TSN) are octahedral and [CuBr(TSN)]Br is five-coordinated. Zinc iodide forms the monomeric compound Znl 2(TSN).

There are no comments yet on this publication. Be the first to share your thoughts.