Affordable Access

Publisher Website

Gas phase anionic ipso substitution reactions of some alkyl phenyl ethers

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
21
Issue
17
Identifiers
DOI: 10.1016/s0040-4039(00)77787-2

Abstract

Abstract It is shown by 18O labelling that phenoxide anions are formed both by an S N2 and a nucleophilic aromatic substitution mechanism in the reaction of OH − with methyl phenyl ether. These mechanisms are of minor importance in the ethyl phenyl ether system where phenoxide anions are generated almost exclusively by an E 2 mechanism.

There are no comments yet on this publication. Be the first to share your thoughts.

Statistics

Seen <100 times
0 Comments

More articles like this

Gas phase reactions of NH2Cl with anionic nucleoph...

on Journal of the American Societ... Jan 01, 2001

Direct measurements of deuterium kinetic isotope e...

on Journal of the American Chemic... May 02, 2007
More articles like this..