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Schwingungsspektren und kraftkonstanten von halogendisilanen

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
26
Issue
4
Identifiers
DOI: 10.1016/0584-8539(70)80278-1

Abstract

Abstract Infrared and Raman spectra of Si 2Cl 6, Si 2Br 6, and Si 2I 6 have been measured. A normal co-ordinate analysis has been made using a valence force field with some constraints. It suggests an increasing SiSi stretching force constant in the series (Si 2H 6<) Si 2I 6 < Si 2Br 6 < Si 2Cl 6 caused by second order hybridization and by interaction of silicon d-orbitals.

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