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Dielectric dispersion in optical electron transfer in solution

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
96
Issue
6
Identifiers
DOI: 10.1016/0009-2614(83)80059-1
Disciplines
  • Physics

Abstract

Abstract Dielectric dispersion causes the outer-sphere reorganization free energy to vary with photon energy in optical electron transfer. The resulting distortion of the spectral response for photoelectron emission may yield misleading evidence about the emission yield versus photon energy relationship. Dispersion is taken into account in the calculation of emission threshold energies and the correlation between optical and thermal electron transfer. Results are given for V 2+, Cr 2+, Mn 2+, Fe 2+, Co 2+, Fe(CN) 6 4−.

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