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Infrared spectra of pentacyanonitrosylmanganate(3−) in K3[M(CN)6] (M  Fe, Co) matrices

Authors
Journal
Spectrochimica Acta Part A Molecular Spectroscopy
0584-8539
Publisher
Elsevier
Publication Date
Volume
51
Issue
4
Identifiers
DOI: 10.1016/0584-8539(94)00150-a

Abstract

Abstract IR spectra of pentacyanonitrosylmanganate(3−) incorporated in potassium hexacyanometallate(3−) (metal = Fe, Co) matrices are obtained. The triplet structure exhibited by the NO stretching band (covering a range of about 35 cm −) can be assigned to anisotropic host lattice effects, confirming the sensitivity of this vibration to the crystal environment as previously found for the nitroprusside or pentacyanonitrosylferrate(2−) anion incorporated in the same matrices.

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