Affordable Access

Publisher Website

Solid state studies:XXVIII. Raman intensity anomalies and intermediate mode behaviour in the ν(CO) region in mixed crystals of M(CO) 5X (M = Mn, Re; X = Cl, Br)

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
249
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)98808-9

Abstract

Abstract The Raman spectra of mixed cyrstals containing Mn(CO) 5X (X = Cl, Br) and Re(CO) 5X′ (X′ = Br, Cl) show band broadening and both band weakening and enhancement in the ca. 1975 cm −1 region. These phenomena are associated with weak vibrational coupling between micro-domains of the pure components in the crystal and, thus, with so-called intermediate-mode coupling

There are no comments yet on this publication. Be the first to share your thoughts.