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(meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra­aza­cyclo­tetra­deca­ne)nickel(II) bis­[O,O′-bis­(4-methyl­phen­yl) thio­phosphate]

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
67
Issue
1
Identifiers
DOI: 10.1107/s1600536810051184
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

In the centrosymmetric title complex, [Ni(C16H36N4)](C14H14O3PS)2, the NiII ion is coordinated by four N atoms and two O atoms within a slightly distorted NiN4O2 octa­hedral geometry. The asymmetric unit consits of one NiII ion that is located on a center of inversion, half of the macrocylic ligand and one anion occupying general positions. Intra­molecular N—H⋯O and N—H⋯S hydrogen bonding is found between the macrocyclic ligand and the monothio­phosphate anion.

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