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A new synthetic method for an acromelic acid analog, a potent neuroexcitatory kainoid amino acid, via photoinduced benzyl radical cyclization

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
43
Issue
43
Identifiers
DOI: 10.1016/s0040-4039(02)01817-8
Keywords
  • Benzyl Radical
  • Radical Cyclization
  • Photoreaction
  • Salt Effect
  • Kainoid

Abstract

Abstract A new synthetic method for an acromelic acid analog, MFPA, was developed. The key step is the photoinduced benzyl radical cyclization with excellent stereoselectivity.

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