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Tetra­aqua­diazido­cobalt(II) 4,4′-dicarboxyl­ato-1,1′-ethyl­enedi­pyridinium dihydrate

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
65
Issue
12
Identifiers
DOI: 10.1107/s1600536809049848
Keywords
  • Metal-Organic Papers
Disciplines
  • Mathematics

Abstract

In the title compound, [Co(N3)2(H2O)4]·C14H12N2O4·2H2O, the metal complex mol­ecule is centrosymmetric, the Co(II) ion being six-coordinated by two azide N atoms and four aqua O atoms with a trans-octa­hedral geometry. The zwitterionic organic mol­ecule is also centrosymmetric. In the crystal, the components are associated into a two-dimensional network through O—H⋯O hydrogen bonds. Further O—H⋯O and O—H⋯N inter­actions give a three-dimensional structure. The free water molecule is disordered over two positions in a 0.787 (5):0.213 (5) ratio.

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