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Aziridinofullerene: a versatile platform for functionalized fullerenes.

Authors
Type
Published Article
Journal
Journal of the American Chemical Society
0002-7863
Publisher
American Chemical Society
Publication Date
Volume
133
Issue
8
Pages
2402–2405
Identifiers
DOI: 10.1021/ja111213k
PMID: 21302952
Source
Medline

Abstract

An aziridine moiety on the fullerene core can serve as an acid-triggered reacting template for the controlled synthesis of a range of functionalized fullerenes that are otherwise difficult to synthesize in an efficient and selective manner. A copper-catalyzed aziridination of C(60) for the practical synthesis of aziridinofullerene 1 and acid-catalyzed reactions of 1 with mono- and bifunctional nucleophiles as well as alkynes are described. The rapid generation of structural diversity in a single chemical operation using the common platform 1 is notable.

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