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An azido-Cu(II)-triazolate complex with utp-type topological network, showing spin-canted antiferromagnetism.

Authors
  • Li, Jian-Rong
  • Yu, Qun
  • Sañudo, E Carolina
  • Tao, Ying
  • Bu, Xian-He
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
Jul 07, 2007
Issue
25
Pages
2602–2604
Identifiers
PMID: 17579751
Source
Medline
License
Unknown

Abstract

An azido-metal-1,2,4-triazolate coordination polymer, [Cu(trz)(N(3))](n) (trz = 1,2,4-triazolate) was synthesized using hydrothermal methods; the complex has a rare three-dimensional non-interpenetrated utp or (10,3)-d topological network structure and exhibits spin-canted antiferromagnetism at low temperature.

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