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Azide ion recognition in water-CHCl(3) using a chelating phosphonium borane as a receptor.

Authors
  • Kim, Youngmin
  • Hudnall, Todd W
  • Bouhadir, Ghenwa
  • Bourissou, Didier
  • Gabbaï, François P
Type
Published Article
Journal
Chemical communications (Cambridge, England)
Publication Date
Jul 07, 2009
Issue
25
Pages
3729–3731
Identifiers
DOI: 10.1039/b905232a
PMID: 19557263
Source
Medline
License
Unknown

Abstract

In H(2)O-CHCl(3), the phosphonium borane [ortho-(Mes(2)B)C(6)H(4)(PMePh(2))](+) selectively complexes azide anions to afford ortho-(Mes(2)(N(3))B)C(6)H(4)(PMePh(2)) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.

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