In H(2)O-CHCl(3), the phosphonium borane [ortho-(Mes(2)B)C(6)H(4)(PMePh(2))](+) selectively complexes azide anions to afford ortho-(Mes(2)(N(3))B)C(6)H(4)(PMePh(2)) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.
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This record was last updated on 07/04/2016 and may not reflect the most current and accurate biomedical/scientific data available from NLM.
The corresponding record at NLM can be accessed at https://www.ncbi.nlm.nih.gov/pubmed/19557263