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Analytical challenges in the quantitative determination of 2H/1H ratios of methyl iodide.

Authors
  • Feakins, Sarah J
  • Rincon, Miguel
  • Pinedo, Paulina
Type
Published Article
Journal
Rapid Communications in Mass Spectrometry
Publisher
Wiley (John Wiley & Sons)
Publication Date
Feb 15, 2013
Volume
27
Issue
3
Pages
430–436
Identifiers
DOI: 10.1002/rcm.6465
PMID: 23280974
Source
Medline
License
Unknown

Abstract

We have refined an earlier method to measure the δ(2)H values of CH(3)I by GC/P/IRMS by adding a cold trap to remove HI. This approach should facilitate future experimentation with the measurement of CH(3)I liberated from natural samples for potentially diverse applications including forensic sourcing of wood and tree-wood-based reconstructions of source water.

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