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Theory and application of photoelectron spectroscopy:XLIV. A quantitative account of hyperconjugation in allyl and benzyl compounds of elements of Group IVB

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
67
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)93659-3

Abstract

Abstract It is shown that the destabilization of the π-MOs in allyl and benzyl compounds of elements M of Group IVB can be quantitatively predicted on the basis of the hyperconjugative M—C/π interaction model.

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