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Potential energy curves in the electron—vibron model

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
194
Identifiers
DOI: 10.1016/0009-2614(92)86059-q
Disciplines
  • Mathematics

Abstract

Abstract A procedure to extract potential energy surfaces associated with electronic states in the molecular electron—vibron model is presented. A coherent state is used to accommodate a Born—Oppenheimer approximation in the algebraic framework. Potential curves for the OH and NH molecules are shown as examples of this approach.

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