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Synthesis and structures of the triple-decker type complexes CpCo(μ-1,3-C3B2Me5)MX2L (M = Rh and Ir; X = Cl and Br; L = Me2SO and PPh3)

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
715
Identifiers
DOI: 10.1016/j.jorganchem.2012.06.003
Keywords
  • Boron
  • Cobalt
  • Heterocycles
  • Rhodium
  • Iridium
  • Triple-Decker Complexes

Abstract

Graphical abstract The title compounds were synthesized by reactions of halides [CpCo(μ-1,3-C3B2Me5)MX2]2 with 2-electron ligands. All complexes were structurally characterized. The Me2SO ligand is S-bonded to the metal atom in the solid state and O-bonded in solution. Highlights ► The title compounds were synthesized by reactions of halides [CpCo(μ-1,3-C3B2Me5)MX2]2 with 2-electron ligands. ► All complexes were structurally characterized. ► The Me2SO ligand is S-bonded to the metal atom in the solid state and O-bonded in solution.

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