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Studies towards a postulated biomimetic Diels-Alder reaction for the synthesis of himgravine

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
36
Issue
52
Identifiers
DOI: 10.1016/0040-4039(95)02045-4
Disciplines
  • Chemistry

Abstract

Abstract The possible role of an iminium ion mediated Diels-Alder reaction on the biosynthetic pathway to himgravinc is discussed. The results of a preliminary investigation of a related oxycarbenium ion mediated Diels-Alder reaction are reported and are in accord with the stereochemistry of the natural product.

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