Affordable Access

Publisher Website

The synthesis of 3-acetamido-2,3,5,6-tetradeoxy-5-fluoro-d,l-ribo-hexofuranose by the direct fluorination of methyl 3-acetamido-2,3,6-trideoxy-d,l-arabino-hexopyranoside (methylN-acetyl-d,l-acosaminide)

Authors
Journal
Carbohydrate Research
0008-6215
Publisher
Elsevier
Publication Date
Volume
132
Issue
2
Identifiers
DOI: 10.1016/0008-6215(84)85220-9

Abstract

Abstract 3-Acetamido-2,3,5,6-tetradeoxy-5-fluoro-d,l-ribo-hexofuranose was synthesized by direct, fluorinative dehydroxylation of methyl 3-acetamido-2,3,6-trideoxy-d,l-arabino-hexopyranoside with sulfur tetrafluoride-hydrogen fluoride. The furanose form and the ribo configuration, indicated by 13C- and 1H-n.m.r. spectroscopy, respectively, were confirmed by a single-crystal, X-ray diffraction study.

There are no comments yet on this publication. Be the first to share your thoughts.