Affordable Access

Publisher Website

The Mechanisms of Jahn–Teller Complex Reorientations

Authors
Publisher
Elsevier Science & Technology
Identifiers
DOI: 10.1016/s0065-3276(03)44031-8

Abstract

Abstract The process of reorientations of the Jahn–Teller (JT) complex with trigonal site symmetry as well as slightly elongated and compressed ones are studied by X-band and Q-band electron paramagnetic resonance (EPR). The observed phenomena of the resonance line broadening and the dispersion of the resonance signal followed by its coalescence are discussed taking into consideration the increase in the transition rate with a rise in temperature. We conclude that even for a complex located at low symmetry sites the transitions between JT conformations can have a tunneling character.

There are no comments yet on this publication. Be the first to share your thoughts.

Statistics

Seen <100 times
0 Comments

More articles like this

Second-order Jahn-Teller effect in a host-guest co...

on Angewandte Chemie Internationa... 2007

Jahn-Teller effect in trinuclear complexes

on Physics Letters A Jan 01, 1974

DFT study of the Jahn–Teller effect in Cu(II) chel...

on Journal of Molecular Structure... Jan 01, 2010

On the jahn-teller effect in binuclear cu(ii) comp...

on Proceedings of the National Ac... March 1968
More articles like this..