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ZrO2−xSx: Stabilization of cubic ZrO2by a partial exchange of oxygen by sulfur

Authors
Journal
Journal of Alloys and Compounds
0925-8388
Publisher
Elsevier
Publication Date
Volume
259
Identifiers
DOI: 10.1016/s0925-8388(97)00122-9
Keywords
  • Fluorite-Type Zirconia
  • Oxide-Sulfide Solid Solution

Abstract

Abstract The cubic, fluorite-type, structure of zirconia has been found to be stabilized at room-temperature by the substitution of the sulfur for oxygen at 20% of the anion sites in a random way. A major effect of this substitution is to increase the ZrZr distances and thereby to decrease the metal-metal interactions contributing to the structural stability of the monoclinic form.

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