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Reprint of: Quantum yield of chlorine-atom formation in the photodissociation of chlorine peroxide (ClOOCl) at 308 nm

Authors
Journal
Chemical Physics Letters
0009-2614
Publisher
Elsevier
Publication Date
Volume
589
Identifiers
DOI: 10.1016/j.cplett.2013.08.067
Disciplines
  • Physics

Abstract

Abstract The production of Cl atoms in the laser flash photolysis of ClOOCl at 308nm has been investigated by time-resolved atomic resonance fluorescence at 235K. A value of ϕ=1.03±0.12 has been obtained for the primary quantum yield based on an absorption cross section ratio σ245/σ308=22 for ClOOCl at 245 and 308nm.

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