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Measurements of VLE,vEandhEfor binary mixtures of n-alkanes with chloro-alkylbenzenes

Authors
Journal
Fluid Phase Equilibria
0378-3812
Publisher
Elsevier
Publication Date
Volume
39
Issue
3
Identifiers
DOI: 10.1016/0378-3812(88)85010-6
Disciplines
  • Physics

Abstract

Abstract Results of a series of experimental investigations of the binary mixtures n-heptane—chlorobenzene and n-octane—benzyl chloride are reported: T, p, x, y data of vapour—liquid equilibria (VLE); h E, T, x data of calorimetric measurements and v, T, x data of volumetric measurements. VLE data are checked for thermodynamic consistency and used to fit parameters of several g E models. UNIFAC predictions and experimental data are compared. h E and v E data were correlated with Redlich-Kister polynomials.

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