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Reactions of small molecules with transition metal cluster hydrides. The reaction of H2Os3(CO)10with aryl-isocyanates and -isothiocyanates

Authors
Journal
Journal of Organometallic Chemistry
0022-328X
Publisher
Elsevier
Publication Date
Volume
171
Issue
1
Identifiers
DOI: 10.1016/s0022-328x(00)88076-6

Abstract

Abstract The transition metal cluster hydride complex H 2Os 3(CO) 10 reacts with aryl isocyanates and isothiocyanates to yield products containing N-aryl-formamido and -thioformamido ligands. The compound (μ-p-CH 3C 6H 4NC(H)O) (μ-H)Os 3(CO) 10 has been analyzed by x-ray crystallographic methods and is shown to contain a formamido ligand bridging the edge of the triosmium cluster.

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