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Formation constants of the tetrazido cuprate(II) and triazido cuprate(I) ions in sodium azide solutions of ionic strength 4·0

Authors
Journal
Journal of Inorganic and Nuclear Chemistry
0022-1902
Publisher
Elsevier
Publication Date
Volume
34
Issue
6
Identifiers
DOI: 10.1016/0022-1902(72)80543-8

Abstract

Abstract The formation constants of tetrazido cuprate(II) and triazido cuprate(I) anions determined by polarographic and potentiometric measurements were found to be respectively 5·8. 10 7 M −3 and 6·5 . 10 7 M −4, at 25·0°C in sodium azide solution of ionic strength 4·0 M. Formal potentials of various copper systems and the disproportionating constant of cuprous ions were determined.

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