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Space group revsion of the triclinic polymorph of salicyl­aldehyde azine

Authors
Journal
Acta Crystallographica Section E Structure Reports Online
1600-5368
Publisher
International Union of Crystallography
Publication Date
Volume
68
Issue
2
Identifiers
DOI: 10.1107/s160053681105478x
Keywords
  • Organic Papers

Abstract

The structure of the title compound, C14H12N2O2 {systematic name: 2,2′-[hydrazinediylidenebis(methanylyl­idene)]diphen­ol}, has already been determined in the triclinic space group P with Z = 4 [El-Medani, Aboaly, Abdalla & Ramadan (2004 ▶). Spectrosc. Lett. 37, 619–632]. However, the correct space group should be P21/c with Z = 4. This structure is a new polymorph of the already known monoclinic polymorph of salicyladehyde azine, which crystallizes in space group P21/n with Z = 2. The benzene rings form a dihedral angle of 46.12 (9)°. Two intramolucular O—H⋯N hydrogen bonds occur.

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