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Supramolecular assembly of ligand-directed triangular {Cu<sup>II</sup><sub>3</sub>Cl} clusters with spin frustration and spin-chain behaviour

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  • Qd Chemistry


Triangular {CuII3Cl} clusters, containing a chloro ligand in an unprecedented trigonal planar coordination mode, are assembled in a 3-D array by the combination of coordinative and hydrogen-bonded interactions, which result in magnetically isolated 1-D chains exhibiting a combination of spin frustration and spin-chain behaviour.

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