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The effects of vibrational relaxation on oxygen K-emission spectra short-wave structure of chelate complexes

Authors
Journal
Journal of Electron Spectroscopy and Related Phenomena
0368-2048
Publisher
Elsevier
Publication Date
Volume
68
Identifiers
DOI: 10.1016/0368-2048(94)02120-1
Disciplines
  • Physics

Abstract

Abstract The electronic structure of the boron mono-β-diketonates and aluminium tris-β-diketonates was investigated by using X-Ray emission spectroscopy and ultraviolet photoelectron spectroscopy of the vapours. The experimental data were compared with the results of theoretical calculations (AM1 and MINDO/3 methods). The effects of vibrational relaxation on OK α spectra short-wave structure of chelate compounds and its connection with the localization degree of highest occupied molecular orbital are discussed.

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