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Total synthesis of (±)-helminthosporal via fragmentation reaction

Authors
Journal
Tetrahedron Letters
0040-4039
Publisher
Elsevier
Publication Date
Volume
32
Issue
46
Identifiers
DOI: 10.1016/s0040-4039(00)93591-3

Abstract

Abstract A new route for the total synthesis of (±)-helminthosporal ((±)- 1), involving fragmentation reaction of tricyclo[3.2.1.0 2,7]octane derivative 5 to give bicyclo[3.2.1]octane derivative 6 as a crucial step, is described.

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