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Optical property modification of ruby and sapphire by N-ion implantation

Authors
Journal
Surface and Coatings Technology
0257-8972
Publisher
Elsevier
Publication Date
Volume
196
Identifiers
DOI: 10.1016/j.surfcoat.2004.08.115
Keywords
  • Optical Property
  • Ruby
  • Sapphire
  • N-Ion Implantation
  • Temperature
  • Optical Absorption
  • Refractive Index
  • Gemological Modification
Disciplines
  • Earth Science

Abstract

Abstract Effects of N-ion implantation on surface modification of synthetic single crystalline ruby (Cr-doped Al 2O 3) and sapphire (α-Al 2O 3) were studied. N ions at energy 120 keV were implanted to samples with doses ranging from 1×10 16 to 1×10 18 ions/cm 2. Temperature studies ruled out the effect of ion-beam heating and, therefore, the gemological modification was the direct result of the implanted ions and radiation damage. Optical measurements showed that the optical absorption of the ion-implanted ruby uniformly increased without observable characteristic changes in any wavelength bands, whereas for the high-dose ion-implanted sapphire, optical absorption in the short wavelength region became stronger. The refractive indices however showed the same decreasing trend in the higher dose ion-implanted samples for both types of crystals. N-ion implantation also caused blistering of the surface, as studied by scanning electron microscopy (SEM). The medium-dose (5×10 17 ions/cm 2) ion-implanted surfaces started to show drastic blistering, and the high-dose (1×10 18 ions/cm 2) ion implantation further resulted in amorphization of the ruby and sapphire surfaces. According to these data, the optical property changes are then attributed to the gem-material surface modification.

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